Might mean blown headgasket or crack head/block. Get the tests done below
Have it block and pressure tested-do the block first to pinpoint a combustion leaking into the cooling system or a gas analyzer to sniff for hydrocarbons at the radiator fill neck.
Pressure test: do not do a pressure test if there's leakage at the headgasket this might cause coolant into the cylinders and lock it up or bend a connecting rod if cranked thereafter. The headgasket should be repaired before doing the pressure test.