How air-conditioner works even after car is not in use

In a very basic form this is how it works,

Principles of Refrigeration

Liquids absorb heat when changed from liquid to gas

Gases give off heat when changed from gas to liquid.

For an air conditioning system to operate with economy, the refrigerant must be used repeatedly. For this reason, all air conditioners use the same cycle of compression, condensation, expansion, and evaporation in a closed circuit. The same refrigerant is used to move the heat from one area, to cool this area, and to expel this heat in another area.

The refrigerant comes into the compressor as a low-pressure gas, it is compressed and then moves out of the compressor as a high-pressure gas.

The gas then flows to the condenser. Here the gas condenses to a liquid, and gives off its heat to the outside air.

The liquid then moves to the expansion valve under high pressure. This valve restricts the flow of the fluid, and lowers its pressure as it leaves the expansion valve.

The low-pressure liquid then moves to the evaporator, where heat from the inside air is absorbed and changes it from a liquid to a gas.

This should help you understand how it works.

https://www.2carpros.com/articles/how-a-car-air-conditioner-works

Great job MHPAUTOS!